Sequenced reactions with samarium(II) iodide, intermolecular ketyl-olefin coupling intramolecular nucleophilic acyl substitution for the preparation of six-, seven-, and eight-membered carbocycles

被引：25

作者：

Molander, GA ^{[1
]}

Sono, M ^{[1
]}

机构：

[1] Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA

来源：

TETRAHEDRON | 1998年 / 54卷 / 32期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4020(98)00584-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A samarium(II) iodide-promoted sequence consisting of an intermolecular ketyl-olefin coupling followed by an intramolecular nucleophilic acyl substitution is described. This process leads to functionalized six- to eight-membered monocyclic and bicyclic ring systems in moderate to good yields. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：9289 / 9302

页数：14

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