Cellulose in lithium chloride/N,N-dimethylacetamide, optimisation of a dissolution method using paper substrates and stability of the solutions

Activation and dissolution in lithium chloride/N,N-dimethylacetamide (LiCl/DMAc) of cellulose from paper substrates are studied. The importance of the multiple parameters involved such as salt concentration, sample source and preparation is shown in a literature review. The experiments are carried out in order to perfect the method of activation and dissolution of paper containing different kinds of additives, typically found in historic papers. The suitability and efficiency obtained in the different trials are evaluated. The final procedure involves the activation by solvent exchange, with a water/methanol/DMAc sequence, followed by dissolution in 8% LiCl/DMAc at 4 degreesC. A study of the stability of the cellulose solutions in the experimental conditions showed that no degradation nor aggregation occurred during the solvation process and even after several months and confirmed the non-aggressiveness of LiCl/DMAc. (C) 2003 Elsevier Science Ltd. All rights reserved.