Layered double hydroxide intercalate of metal-chelate complex - a novel precursor for the formation of a mixed metal oxide

被引：17

作者：

Kaneyoshi, M ^{[1
]}

Jones, W ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2001年 / 356卷

关键词：

intercalation; LDH; anionic clay; chelate; lanthanum oxide; thermal decomposition;

D O I：

10.1080/10587250108023724

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of a nitrilotriacetate-intercalated Mg-Al layered double hydroxide in a lanthanum nitrate solution is studied. La3+ is incorporated into the interlayer through the formation of a chelate complex. NO3- is also taken up as a charge-balancing anion. During chelation the interlayer repeat increases from 11.9 A to 13.9 A. Chemical analysis suggests that 1:1 and 1:2 metal:chelate complexes are formed within the interlayer. Calcination of the La3+-containing double hydroxide results in the formation of LaAlO3.

引用

页码：459 / 468

页数：10

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