Chiral base-mediated rearrangement of meso-cyclohexene oxides to allylic alcohols

被引：31

作者：

OBrien, P

Poumellec, P

机构：

[1] Department of Chemistry, University of York, Heslington

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 44期

关键词：

D O I：

10.1016/0040-4039(96)01824-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Highly enantiomerically enriched allylic alcohols have been generated by rearranging single diastereomers of meso-cyclohexene oxides using a homochiral lithium amide base. PDC oxidation of each allylic alcohol product affords a different enantiomer of a synthetically useful cyclohexenone. Copyright (C) 1996 Elsevier Science Ltd

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页码：8057 / 8058

页数：2

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