A novel flow battery - A lead acid battery based on an electrolyte with soluble lead(II) - III. The influence of conditions on battery performance

被引:124
作者
Pletcher, D [1 ]
Wills, R [1 ]
机构
[1] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England
关键词
flow batteries; lead acid; methanesulfonic acid;
D O I
10.1016/j.jpowsour.2005.01.048
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The performance of an undivided flow battery based on the Pb(II)/Pb and PbO2/Pb(II) couples in aqueous methanesulfonic acid as a function of state of charge, current density, electrolyte flow rate and temperature is reported. ln addition, it is demonstrated that the cell chemistry can be rebalanced after multiple charge/discharge by allowing the excess lead metal deposited at the negative electrode to react with oxygen on open circuit. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:96 / 102
页数:7
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