Can block copolymers be synthesized by a single-step chemoenzymatic route in supercritical carbon dioxide?

被引：104

作者：

Duxbury, CJ

Wang, WX

de Geus, M

Heise, A

Howdle, SM

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

[2] Eindhoven Univ Technol, Dept Polymer Chem, NL-5600 MB Eindhoven, Netherlands

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 08期

关键词：

D O I：

10.1021/ja042903o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We demonstrate the single-step one-pot synthesis of block copolymers by simultaneous enzymatic ring-opening polymerization and chemically catalyzed atom transfer radical polymerization in supercritical carbon dioxide. Both catalyst systems function simultaneously under these conditions, providing a simple route to the formation of block copolymers of dissimilar monomers. Copyright © 2005 American Chemical Society.

引用

页码：2384 / 2385

页数：2

共 18 条

[1] Polymer synthesis and processing using supercritical carbon dioxide [J].