Electron transfer rate on mixed valence states of Class II/III transition for N,N′-diphenyl-1,4-phenylenediamine structures as a polyaniline unit

被引:6
作者
Nishiumi, T
Nomura, Y
Higuchi, M
Yamamoto, K [1 ]
机构
[1] Kanagawa Acad Sci & Technol, Yokohama, Kanagawa 2238522, Japan
[2] Keio Univ, Fac Sci & Technol, Dept Chem, Yokohama, Kanagawa, Japan
基金
日本学术振兴会;
关键词
D O I
10.1016/S0009-2614(03)01237-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The first example of the determination of the electron transfer rate (lambda, V, DeltaG*, k(th)) for N,N'-diphenyl-1,4-phenylenediamine derivatives using the Marcus-Hush theory is described. These results were in good agreement with the ones obtained using variable-temperature IR spectra measurements. (C) 2003 Elsevier B.V. All rights reserved.
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页码:18 / 23
页数:6
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