Electron transfer rate on mixed valence states of Class II/III transition for N,N′-diphenyl-1,4-phenylenediamine structures as a polyaniline unit

被引：6

作者：

Nishiumi, T

Nomura, Y

Higuchi, M

Yamamoto, K ^{[1
]}

机构：

[1] Kanagawa Acad Sci & Technol, Yokohama, Kanagawa 2238522, Japan

[2] Keio Univ, Fac Sci & Technol, Dept Chem, Yokohama, Kanagawa, Japan

来源：

CHEMICAL PHYSICS LETTERS | 2003年 / 378卷 / 1-2期

基金：

日本学术振兴会;

关键词：

D O I：

10.1016/S0009-2614(03)01237-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The first example of the determination of the electron transfer rate (lambda, V, DeltaG*, k(th)) for N,N'-diphenyl-1,4-phenylenediamine derivatives using the Marcus-Hush theory is described. These results were in good agreement with the ones obtained using variable-temperature IR spectra measurements. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：18 / 23

页数：6

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