Cobalt-catalyzed Alder-ene reaction

被引：88

作者：

Hilt, Gerhard ^{[1
]}

Treutwein, Jonas ^{[1
]}

机构：

[1] Univ Marburg, Fachbereich Chem, D-35043 Marburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 44期

关键词：

Alder-ene reaction; alkenes; alkynes; cobalt; stereoselectivity;

D O I：

10.1002/anie.200703180

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Next reactant, new pathway: An inexpensive cobalt-diphosphine complex is able to catalyze the intermolecular Alder-ene reaction of internal alkynes with terminal alkenes. The products are functionalized 1,4-dienes (see scheme) which are obtained in good yields and with excellent chemo-, regio-, and stereoselectivities. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8500 / 8502

页数：3

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