Initiated chemical vapor deposition of poly(furfuryl methacrylate)

被引:24
作者
Chen, Guohua [1 ]
Gupta, Malancha [1 ]
Chan, Kelvin [1 ]
Gleason, Karen K. [1 ]
机构
[1] MIT, Dept Chem Engn, Cambridge, MA 02139 USA
关键词
Diels-Alder polymers; functionalization of polymers; polymerization; thin films;
D O I
10.1002/marc.200700466
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Furan ring-functionalized solid surfaces are achieved by the initiated chemical vapor deposition (iCVD) method, a solvent-free process to form films under mild conditions. The polymerization of furfuryl methacrylate monomer is initiated by a resistively heated filament wire. The functionality of the furan group in the iCVD film enabled Diels-Alder chemistry with 4-phenyl-1,2,3-triazolin-3,5-dione (N-PTD).
引用
收藏
页码:2205 / 2209
页数:5
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