Chemical polymerization of 3,4-ethylenedioxythiophene using an aqueous medium containing an anionic surfactant

被引：47

作者：

Kudoh, Y ^{[1
]}

Akami, K ^{[1
]}

Matsuya, Y ^{[1
]}

机构：

[1] Matsushita Res Inst Tokyo Inc, Adv Mat Res Lab, Tama Ku, Kawasaki, Kanagawa 214, Japan

来源：

SYNTHETIC METALS | 1998年 / 98卷 / 01期

关键词：

poly(3,4-ethylenedioxythiophene); emulsion polymerization; anionic surfactant; conductivity; environmental stability;

D O I：

10.1016/S0379-6779(98)00148-9

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We found that a good yield of poly(3,4-ethylenedioxythiophene) (PEDOT) was obtained by emulsion polymerization in which an anionic surfactant and Fe(2)(SO(4))(3) were used as an emulsifier and an oxidant, respectively. The major feature of this polymerization is that highly conductive PEDOT is formed in an aqueous medium containing such a low concentration of 3,4-ethylenedioxythiophene (EDOT) and Fe(2)(SO(4))(3) as 0.05 M. This is most likely due to the polymerization progressing in the innumerable micelles where hydrophobic EDOT is concentrated. The thermal stability of PEDOT obtained here is superior to that of polypyrrole prepared in a similar manner, although its moisture stability is inferior. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：65 / 70

页数：6

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