ZnMn2O4 nanoparticles synthesized by a hydrothermal method as an anode material for Li-ion batteries

被引：122

作者：

Courtel, Fabrice M. ^{[1
]}

Abu-Lebdeh, Yaser ^{[1
]}

Davidson, Isobel J. ^{[1
]}

机构：

[1] Natl Res Council Canada, Ottawa, ON K1A 0R6, Canada

来源：

ELECTROCHIMICA ACTA | 2012年 / 71卷

关键词：

ZnMn2O4; Hydrothermal; Li-ion batteries; Nanoparticles; Anode material; SN-C COMPOSITE; NEGATIVE ELECTRODES; MIXED OXIDES; LITHIUM; PERFORMANCE; MORPHOLOGY; CELLULOSE; STORAGE; TEMPERATURE; STABILITY;

D O I：

10.1016/j.electacta.2012.03.108

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

ZnMn2O4 nanoparticles prepared by a hydrothermal synthesis were evaluated as anode material for Li-ion batteries. XRD measurements showed that a ZnMn2O4 I4(1)/amd tetragonal spinel structure was obtained with crystallite sizes <= 5 nm. TEM micrographs showed that particles of about 5 nm in diameter were synthesized. Li/ZnMn2O4 half cell battery cycling showed that the nanoparticles, using lithium salt of carboxymethylcellulose as binder, give a high capacity of 430 mAh g(-1) when cycled 100 times at C/10. Crown Copyright (C) 2012 Published by Elsevier Ltd. All rights reserved.

引用

页码：123 / 127

页数：5

共 56 条

[1] Changes in oxidation state and magnetic order of iron atoms during the electrochemical reaction of lithium with NiFe2O4 [J].

Alcántara, R ;

Jaraba, M ;

Lavela, P ;

Tirado, JL ;

Jumas, JC ;

Olivier-Fourcade, J .

ELECTROCHEMISTRY COMMUNICATIONS, 2003, 5 (01) :16-21

[2]

AXS Bruker, 2008, BRUKERAXS DIFFRACPLU

[3] Si electrodes for li-ion batteries - A new way to look at an old problem [J].

Beattie, S. D. ;

Larcher, D. ;

Morcrette, M. ;

Simon, B. ;

Tarascon, J. -M. .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (02) :A158-A163

[4] 57Fe Mossbauer Spectroscopy and electron Microscopy study of metal extraction from CuFe2O4 electrodes in lithium cells [J].

Bomio, Mauricio ;

Lavela, Pedro ;

Tirado, Jose Luis .

CHEMPHYSCHEM, 2007, 8 (13) :1999-2007

[5]

Brousse T., 2002, MAT CHEM LITHIUM BAT

[6]

Bruce P.G., 2003, SOLID STATE ELECTROC

[7] Study of styrene butadiene rubber and sodium methyl cellulose as binder for negative electrodes in lithium-ion batteries [J].

Buqa, H. ;

Holzapfel, M. ;

Krumeich, F. ;

Veit, C. ;

Novak, P. .

JOURNAL OF POWER SOURCES, 2006, 161 (01) :617-622

[8] Facile preparation of porous one-dimensional Mn2O3 nanostructures and their application as anode materials for lithium-ion batteries [J].

Cai, Yong ;

Liu, Shuang ;

Yin, Xiaoming ;

Hao, Quanyi ;

Zhang, Ming ;

Wang, Taihong .

PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES, 2010, 43 (01) :70-75

[9] High-performance lithium battery anodes using silicon nanowires [J].

Chan, Candace K. ;

Peng, Hailin ;

Liu, Gao ;

McIlwrath, Kevin ;

Zhang, Xiao Feng ;

Huggins, Robert A. ;

Cui, Yi .

NATURE NANOTECHNOLOGY, 2008, 3 (01) :31-35

[10] A FUNDAMENTAL PARAMETERS APPROACH TO X-RAY LINE-PROFILE FITTING [J].

CHEARY, RW ;

COELHO, A .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1992, 25 (pt 2) :109-121

← 1 2 3 4 5 6 →