Copper(II) acetate promoted intramolecular diamination of unactivated olefins

被引：186

作者：

Zabawa, TP ^{[1
]}

Kasi, D ^{[1
]}

Chemler, SR ^{[1
]}

机构：

[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 32期

关键词：

D O I：

10.1021/ja053335v

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A concise method for the synthesis of cyclic sulfamides and vicinal diamines is presented. This method is enabled by Cu(OAc)2 and demonstrates a new transformation for this metal. Both five- and six-membered vicinal diamine-containing heterocycles have been synthesized in good to excellent yields, and substrate-based asymmetric induction has been achieved. This is the first reported example of intramolecular diamination of olefins. Copyright © 2005 American Chemical Society.

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页码：11250 / 11251

页数：2

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