Biomimetic Catalysis

被引：216

作者：

Marchetti, Louis ^{[1
]}

Levine, Mindy ^{[1
]}

机构：

[1] Univ Rhode Isl, Dept Chem, Kingston, RI 02881 USA

来源：

ACS CATALYSIS | 2011年 / 1卷 / 09期

关键词：

biomimetic; catalysis; cyclodextrin; polyethyleneimine; hydrophobic effect; MOLECULARLY IMPRINTED POLYMERS; DIELS-ALDER REACTIONS; ANALOGUE BUILT POLYMERS; ENANTIOSELECTIVE CLAISEN REARRANGEMENTS; ASYMMETRIC ALPHA-AMINOXYLATION; ENZYME-LIKE CATALYSIS; AMINO-ACIDS; BETA-CYCLODEXTRIN; TRANSITION-METAL; STETTER REACTION;

D O I：

10.1021/cs200171u

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The field of biomimetic chemistry encompasses a wide variety of subfields, including biomimetic catalysis, bioinspired self-assembly, and biomimetic reactions in total synthesis. Reviewed herein are select examples of biomimetic catalysis using macrocycles and polymeric catalysts. Such catalysts have been used in a variety of synthetic reactions, including several examples of Diels-Alder cycloadditions. Moreover, biomimetic catalysis has influenced the development of the highly active research area of organocatalysis. Several examples of the connections between biomimetic catalysis and organocatalysis are also discussed.

引用

页码：1090 / 1118

页数：29

共 277 条

[1] New strategies for organic catalysis: The first highly enantioselective organocatalytic Diels-Alder reaction [J].