The vibrational state v5=1 of HCOOD

被引：9

作者：

Baskakov, OI ^{[1
]}

机构：

[1] Kharkov Natl Univ, Fac Quantum Radiophys, UA-61077 Kharkov, Ukraine

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 2001年 / 208卷 / 02期

关键词：

formic acid; FTIR spectrum; deuterated;

D O I：

10.1006/jmsp.2001.8390

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The FTIR spectrum of the deuterated formic acid HCOOD was measured in the region 1050-1300 cm(-1) with resolution ca. 0.003 cm(-1). Combined analysis of the 3579 assigned infrared transitions of the nu (5) band centered at 1177.1 cm(-1) and 52 millimeter-wave rotational transitions belonging to the nu (5) = 1 vibrational state made it possible to improve rotational, quartic, and sextic centrifugal distortion parameters. The RMS deviation of the IR transitions is 0.000240 cm(-1). The maximum value of J ' is 67. (C) 2001 Academic Press.

引用

页码：194 / 196

页数：3

共 16 条

[1] The Coriolis-Coupled States υ6=1 and υ8=1 of DCOOH [J].

Baskakov, OI ;

Alanko, S ;

Koivusaari, M .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1999, 198 (01) :40-42

[2] Assignment of some laser transitions in HCOOD molecule [J].

Baskakov, OI .

QUANTUM ELECTRONICS, 1999, 29 (03) :226-228

[3] Rotational spectrum of the excited vibrational states of DCOOH and assignment of optically pumped laser transitions [J].

Baskakov, OI .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1996, 180 (02) :266-276

[4] The Coriolis-coupled states ν7=1 and ν9=1 of trans-HCOOD and of trans-DCOOD [J].

Baskakov, OI ;

Burger, H ;

Jerzembeck, W .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1999, 193 (01) :33-45

[5] MICROWAVE-SPECTRA AND CENTRIFUGAL-DISTORTION CONSTANTS OF FORMIC-ACID CONTAINING C-13 AND O-18 - REFINEMENT OF THE HARMONIC FORCE-FIELD AND THE MOLECULAR-STRUCTURE [J].

DAVIS, RW ;

ROBIETTE, AG ;

GERRY, MCL ;

BJARNOV, E ;

WINNEWISSER, G .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1980, 81 (01) :93-109

[6] The ν3 band of DCOOH [J].

Goh, KL ;

Ong, PP ;

Tan, TL .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1999, 55 (13) :2601-2614

[7] High resolution FTIR spectrum of the ν6 band of deuterated formic acid (DCOOH) [J].

Goh, KL ;

Ong, PP ;

Tan, TL ;

Teo, HH .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1999, 55 (7-8) :1309-1318

[8] Improved rovibrational constants of the ν3 infrared band of HCOOD [J].

Goh, KL ;

Ong, PP ;

Teo, HH ;

Tan, TL .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1999, 197 (02) :322-323

[9] The high-resolution infrared spectrum of the ν5 band of deuterated formic acid (DCOOH) [J].

Goh, KL ;

Ong, PP ;

Tan, TL ;

Wang, WF ;

Teo, HH .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1998, 190 (01) :125-129

[10] High-resolution FTIR spectrum of the ν5 band of HCOOD [J].

Goh, KL ;

Ong, PP ;

Tan, TL ;

Teo, HH ;

Wang, WF .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1998, 191 (02) :343-347

← 1 2 →