Synthesis and structural characterization of layered Li[Ni1/3+xCo1/3Mn1/3-2xMox]O2 cathode materials by ultrasonic spray pyrolysis

被引：74

作者：

Park, SH ^{[1
]}

Oh, SW ^{[1
]}

Sun, YK ^{[1
]}

机构：

[1] Hanyang Univ, Dept Chem Engn, Ctr Informat & Comm Mat, Seoul 133791, South Korea

来源：

JOURNAL OF POWER SOURCES | 2005年 / 146卷 / 1-2期

关键词：

lithium-ion battery; cathode materials; molybdenum doping; layered structure; spray pyrolysis;

D O I：

10.1016/j.jpowsour.2005.03.078

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Molybdenum doped layered Li[Ni1/3+xMn1/3Mn1/3-2xMox]O-2 materials were synthesized by an ultrasonic spray pyrolysis method. A single phase of Li[Ni(1/3+x)Co(1/3)Mn(1/3-2x)Mox]O-2 could be prepared in 0 <= x <= 0.05 region. Structural and electrochemical properties of the Li[Ni1/3+xCo1/3Mn1/3-2xMox]O-2 were characterized by X-ray diffraction, Rietveld refinements and galvanostatic charge/discharge tests. The discharge capacity increased with the molybdenum doped, x in 0.01 sample is exhibited a higher discharge capacity of 175 mAh g(-1) with a good capacity retention. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：622 / 625

页数：4

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