A three-dimensional zeolitic zinc phosphate, [C8N5H28][Zn5(PO4)5]H2O, with thomsonite structure

被引：19

作者：

Neeraj, S ^{[1
]}

Natarajan, S ^{[1
]}

机构：

[1] Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2001年 / 62卷 / 08期

关键词：

D O I：

10.1016/S0022-3697(01)00066-X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new zeolitic zinc phosphate, [C8N5H28][Zn-5(PO4)(5)].H2O, I, has been synthesized hydrothermally in the presence of tetraethylenepentamine (TEPA). The structure consists of vertex linking ZnO4 and PO4 tetrahedral units forming channels bound by eight T-atoms (T = Zn, P). The structure is identical to the naturally occurring aluminosilicate mineral, thomsonite. Crystal data, [NH3(CH2)(2)NH2(CH2)(2)NH2(CH2)(2)NH2(CH2)(2)NH3][Zn-5(PO4)(5)]H2O (I), M=1035.86, monoclinic, space group C2/c (no. 15), a = 14.0189(3), b = 13.4792(4), c = 14.2787(5) Angstrom, beta = 90.466(2)degrees V= 2698.06(14) Angstrom (3), Z= 8, rho (calc) = 2.461 g cm(-3), mu (Mo K alpha) = 4.782 mm(-1), R-1 = 0.0622, wR(2) = 0.1388, [1509 observed reflections with I > 2 sigma (I)]. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：1499 / 1505

页数：7

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