Unveiling Electron Promiscuity

被引：52

作者：

Ben-Amotz, Dor ^{[1
]}

机构：

[1] Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY LETTERS | 2011年 / 2卷 / 10期

基金：

美国国家科学基金会;

关键词：

DENSITY-FUNCTIONAL THEORY; HYDRATED ELECTRON; SOLVATED ELECTRON; MOLECULAR-DYNAMICS; NEAT WATER; INTERFACES; SURFACE; SPECTROSCOPY; BINDING; RADIOLYSIS;

D O I：

10.1021/jz2002875

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Although the wave-like proclivity of electrons for delocalization is familiar to every student of chemistry, it seems that electrons may have less respect for atomic and molecular boundaries than one might have considered proper. The boundaries in question include those between H-bonded dimers and within hydrated clusters, as well as those of aqueous cavities, colloidal suspensions, and macroscopic air-water and oil-water interfaces. Unveiling the promiscuous behavior of electrons at such frontiers may both raise eyebrows and demand acknowledgment.

引用

收藏

页码：1216 / 1222

页数：7

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