Solvent-free self-assembly of C60 and cucurbit[7]uril using high-speed vibration milling

被引：33

作者：

Constabel, F ^{[1
]}

Geckeler, KE ^{[1
]}

机构：

[1] Kwangju Inst Sci & Technol, Dept Mat Sci & Engn, Lab Appl Macromol Chem, Kwangju 500712, South Korea

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 10期

关键词：

C-60; cucurbit[7]uril; solvent free; high-speed vibration milling; solid-state reaction; 60]fullerene;

D O I：

10.1016/j.tetlet.2004.01.071

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of a cucurbit[7]uril-[60]fullerene supramolecule complex using a simple, green, and efficent pathway is reported for the first time. In the complex, which was found to be of the 1:2 type, the compounds interact weekly with each other. Since the complexation can be achieved by a solid-solid reaction without solvent both the waste and contact with harmful solvents can by reduced to a minimum. A significant increase of reaction rate and yield compared to the heterogenous complexation was observed. (C) 2004 Published by Elsevier Ltd.

引用

页码：2071 / 2073

页数：3

共 11 条

[1] MECHANOCHEMISTRY - A NOVEL-APPROACH TO THE SYNTHESIS OF FULLERENE COMPOUNDS - WATER-SOLUBLE BUCKMINSTERFULLERENE-GAMMA-CYCLODEXTRIN INCLUSION COMPLEXES VIA A SOLID-SOLID REACTION [J].