Experimental and theoretical evidence for the formation of several uranium hydride molecules

被引：104

作者：

Souter, PF

Kushto, GP

Andrews, L

Neurock, M

机构：

[1] UNIV VIRGINIA,DEPT CHEM,CHARLOTTESVILLE,VA 22901

[2] UNIV VIRGINIA,DEPT CHEM ENGN,CHARLOTTESVILLE,VA 22901

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1997年 / 119卷 / 07期

关键词：

D O I：

10.1021/ja9630809

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The primary reaction products of laser-ablated uranium atoms with dihydrogen (UH, UH2, UH3, UH4, U2H2, and U2H4) have been isolated for the first time in solid argon and identified by the effects of isotopic substitution on their infrared spectra. Calculations, using DFT methods, have been performed to provide theoretical support for the spectral assignments. The molecules U(mu-H-2)U and U2H4 represent the first examples of an actinide-actinide bond.

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页码：1682 / 1687

页数：6

相关论文

共 42 条

[1]

[Anonymous], [No title captured], DOI DOI 10.1016/0021-9991(92)90277-6

[2] Self-consistent molecular Hartree-Fock-Slater calculations - I. The computational procedure [J].

Baerends, E. J. ;

Ellis, D. E. ;

Ros, P. .

CHEMICAL PHYSICS, 1973, 2 (01) :41-51

[3]

BOERRIGTE PM, 1987, THESIS VRIJE U AMSTE

[4] ORGANO-F-ELEMENT THERMOCHEMISTRY - THORIUM VS URANIUM AND ANCILLARY LIGAND EFFECTS ON METAL-LIGAND BOND DISRUPTION ENTHALPIES IN BIS(PENTAMETHYLCYCLOPENTADIENYL)ACTINIDE BIS(HYDROCARBYLS) AND BIS(PENTAMETHYLCYCLOPENTADIENYL)ALKOXYACTINIDE HYDRIDES AND HYDROCARBYLS [J].

BRUNO, JW ;

STECHER, HA ;

MORSS, LR ;

SONNENBERGER, DC ;

MARKS, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (23) :7275-7280

[5] REACTIONS OF BORON ATOMS WITH MOLECULAR-OXYGEN - INFRARED-SPECTRA OF BO, BO2, B2O2, B2O3, AND BO2- IN SOLID ARGON [J].

BURKHOLDER, TR ;

ANDREWS, L .

JOURNAL OF CHEMICAL PHYSICS, 1991, 95 (12) :8697-8709

[6] CORRELATION BETWEEN GASEOUS ATOMIC SPECTRA AND ABSORPTION-SPECTRA OF ATOMS ISOLATED IN NOBLE-GAS MATRICES [J].

CARSTENS, DH ;

BRASHEAR, W ;

ESLINGER, DR ;

GRUEN, DM .

APPLIED SPECTROSCOPY, 1972, 26 (02) :184-+

[7] METAL METAL BONDS INVOLVING THE F-ELEMENTS .4. MOLECULAR-ORBITAL STUDIES OF METAL METAL AND METAL-LIGAND INTERACTIONS IN DINUCLEAR URANIUM(V) SYSTEMS [J].

CAYTON, RH ;

NOVOGRADAC, KJ ;

BURSTEN, BE .

INORGANIC CHEMISTRY, 1991, 30 (10) :2265-2272

[8] REACTIONS OF PULSED-LASER-EVAPORATED AL WITH C AND C(2)H(2) - INFRARED-SPECTRA AND CASSCF CALCULATIONS FOR ALC, AL2C, AL2C2, AND ALC2H [J].

CHERTIHIN, GV ;

ANDREWS, L ;

TAYLOR, PR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (08) :3513-3518

[9] REACTIONS OF LASER-ABLATED TI ATOMS WITH HYDROGEN DURING CONDENSATION IN EXCESS ARGON - INFRARED-SPECTRA OF THE TIH, TIH2, TIH3, AND TIH4 MOLECULES [J].

CHERTIHIN, GV ;

ANDREWS, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (18) :8322-8327

[10] INFRARED-SPECTRA OF ZRH4 AND HFH4 IN SOLID ARGON [J].

CHERTIHIN, GV ;

ANDREWS, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (23) :6402-6403

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