High-efficiency and air-stable P3HT-based polymer solar cells with a new non-fullerene acceptor

被引：1059

作者：

Holliday, Sarah ^{[1
,2
]}

Ashraf, Raja Shahid ^{[1
,2
]}

Wadsworth, Andrew ^{[1
,2
]}

Baran, Derya ^{[1
,2
]}

Yousaf, Syeda Amber ^{[3
]}

Nielsen, Christian B. ^{[1
,2
]}

Tan, Ching-Hong ^{[1
,2
]}

Dimitrov, Stoichko D. ^{[1
,2
]}

Shang, Zhengrong ^{[4
]}

Gasparini, Nicola ^{[5
]}

Alamoudi, Maha ^{[6
]}

Laquai, Frederic ^{[6
]}

Brabec, Christoph J. ^{[5
]}

Salleo, Alberto ^{[4
]}

Durrant, James R. ^{[1
,2
]}

McCulloch, Iain ^{[1
,2
,6
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

[2] Univ London Imperial Coll Sci Technol & Med, Ctr Plast Elect, London SW7 2AZ, England

[3] Govt Coll Univ, Dept Phys, Lahore 54000, Pakistan

[4] Stanford Univ, Dept Mat Sci & Engn, 476 Lomita Mall, Stanford, CA 94305 USA

[5] Univ Erlangen Nurnberg, Inst Mat Elect & Energy Technol, D-91058 Erlangen, Germany

[6] King Abdullah Univ Sci & Technol, Solar & Photovolta Engn Res Ctr, Thuwal 239556900, Saudi Arabia

来源：

NATURE COMMUNICATIONS | 2016年 / 7卷

基金：

英国工程与自然科学研究理事会;

关键词：

POWER-CONVERSION EFFICIENCY; HIGH-PERFORMANCE; ELECTRON-ACCEPTORS; SEMICONDUCTING POLYMERS; TRANSISTORS; MORPHOLOGY; P3HT; RECOMBINATION; OPTIMIZATION; STABILITY;

D O I：

10.1038/ncomms11585

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Solution-processed organic photovoltaics (OPV) offer the attractive prospect of low-cost, light-weight and environmentally benign solar energy production. The highest efficiency OPV at present use low-bandgap donor polymers, many of which suffer from problems with stability and synthetic scalability. They also rely on fullerene-based acceptors, which themselves have issues with cost, stability and limited spectral absorption. Here we present a new non-fullerene acceptor that has been specifically designed to give improved performance alongside the wide bandgap donor poly(3-hexylthiophene), a polymer with significantly better prospects for commercial OPV due to its relative scalability and stability. Thanks to the well-matched optoelectronic and morphological properties of these materials, efficiencies of 6.4% are achieved which is the highest reported for fullerene-free P3HT devices. In addition, dramatically improved air stability is demonstrated relative to other high-efficiency OPV, showing the excellent potential of this new material combination for future technological applications.

引用

页数：11

共 52 条

[31] Design of Semiconducting Indacenodithiophene Polymers for High Performance Transistors and Solar Cells [J].