A new layered aluminophosphate [C4H12N2][Al2P2O8(OH)2] templated by piperazine

被引：35

作者：

Wang, KX ^{[1
]}

Yu, JH ^{[1
]}

Miao, P ^{[1
]}

Song, Y ^{[1
]}

Li, JY ^{[1
]}

Shi, Z ^{[1
]}

Xu, RR ^{[1
]}

机构：

[1] Jilin Univ, Dept Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2001年 / 11卷 / 07期

关键词：

D O I：

10.1039/b010206g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new layered aluminophosphate with an Al/P ratio of unity, designated AlPO-CJ9 (CJ9: China, Jilin University, number 9), has been synthesized hydrothermally. The crystalline product is characterized by powder and single-crystal X-ray diffraction (XRD), FT-IR and thermogravimetric analyses. The structure of AlPO-CJ9 contains [Al2P2O8(OH)(2)](2-) macroanionic sheets stacked in an AAAA sequence. The inorganic layer based on a 3 x 4 x 6 net is featured by a type of chain built up by corner-sharing three-membered rings. The nonbonding interaction energies (E-inter), including H-bonding, van der Waals and Coulombic interactions between the inorganic layer and several organic amines are studied, which are valuable in evaluating the templating abilities of the organic templates.

引用

页码：1898 / 1902

页数：5

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