Ionic liquids in carbohydrate chemistry - Current trends and future directions

被引:146
作者
Murugesan, S
Linhardt, RJ [1 ]
机构
[1] Rensselaer Polytech Inst, Ctr Biotechnol, Dept Biol & Chem Engn, Troy, NY 12180 USA
[2] Rensselaer Polytech Inst, Dept Chem & Biol Chem, Troy, NY 12180 USA
[3] Rensselaer Polytech Inst, Dept Biol, Troy, NY 12180 USA
关键词
carbohydrates; room temperature ionic liquids; green chemistry; catalysis;
D O I
10.2174/157017905774322640
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Room Temperature Ionic Liquids (RTILs) have recently been introduced as new solvents in the chemical and biotechnological arenas. Carbohydrates are important natural products that play important biological and commercial roles as foods, drugs and chemical feedstocks. They have two properties that complicate their use a low solubility in most solvents and complex, highly chiral structures. We are currently witnessing a rapid increase in novel applications for newly discovered RTILs. This account reviews the application of RTILs in carbohydrate chemistry and biochemistry as a mono / biphasic solvent, a solvent catalyst and a product retrieval media.
引用
收藏
页码:437 / 451
页数:15
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