Syntheses and Magnetic Properties of 1,4,8,11-Tetraazacyclotetradecanenickel(II) Tetra-, Hexa-, and Octa-cyanometalates

被引：26

作者：

Nowicka, Beata ^{[2
]}

Hagiwara, Masayuki ^{[1
]}

Wakatsuki, Yasuo ^{[1
]}

Kisch, Horst ^{[2
]}

机构：

[1] RIKEN, Inst Phys & Chem Res, Wako, Saitama 3510198, Japan

[2] Univ Erlangen Nurnberg, Inst Inorgan Chem, D-91058 Erlangen, Germany

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1999年 / 72卷 / 03期

关键词：

D O I：

10.1246/bcsj.72.441

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of 1,4,8,11-tetraazacyclotetradecanenickel(II) cyanometalates ([Ni(cyclam)](3) [Fe(CN)(6)](2)center dot 11H(2)O (1), [Ni-(cyclam)](2)[Mo(CN)(3)]center dot 3H(2)O (2), [Ni(cyclam)](2)[W(CN)(8)]center dot 3H(2)O (3), and [Ni(cyclam)](2)[W(CN)(8)]center dot 3H(2)O (4) (cyclam = 1,4, 8,11-tetraazaeyelotetradecane)) was obtained and characterised. Magnetic-susceptibility measurements showed a high-spin configuration (S = 1) of N(II) in all compounds, which was attributed to the interaction of cyano ligands with free axial coordination sites on nickel. The presence of bridging cyano groups in 1 was confirmed by IR and visible reflectance spectra. Compound 1 shows a long-range magnetic order below 8 K.

引用

页码：441 / 445

页数：5

共 32 条

[1] COMPLEXES OF NICKEL(2) WITH A CYCLIC TETRADENTATE SECONDARY AMINE [J].

BOSNICH, B ;

TOBE, ML ;

WEBB, GA .

INORGANIC CHEMISTRY, 1965, 4 (08) :1109-&

[2] MOLECULAR STRUCTURE OF DICHLORO-1,4,8,11-TETRA-AZACYCLOTETRADECANENICKEL(2) [J].

BOSNICH, B ;

MASON, R ;

PAULING, PJ ;

ROBERTSO.GB ;

TOBE, ML .

CHEMICAL COMMUNICATIONS, 1965, (06) :97-&

[3] FERROMAGNETIC INTERACTIONS IN DECAMETHYLFERROCENIUM SALTS OF NICKEL BIS(DICHALCOGOLENES) [J].

BRODERICK, WE ;

THOMPSON, JA ;

GODFREY, MR ;

SABAT, M ;

HOFFMAN, BM ;

DAY, EP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (19) :7656-7657

[4] METAMAGNETIC PROPERTIES OF ONE-DIMENSIONAL DECAMETHYLFERROCENIUM 7,7,8,8-TETRACYANO-P-QUINODIMETHANIDE (1-1)-[FE(ETA5-C5ME5)2]+.(TCNQ)-. [J].

CANDELA, GA ;

SWARTZENDRUBER, LJ ;

MILLER, JS ;

RICE, MJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (10) :2755-2756

[5]

CARLIN RL, 1991, COMMENTS INORG CHEM, V11, P215

[6] A cyano bridged iron(III) linear chain with alternating Fe(CN)6-Fe(cyclam) (cyclam = 1,4,8,11-tetraazacyclodecane) units and unexpected ferromagnetic behaviour [J].

Colacio, E ;

Domínguez-Vera, JM ;

Ghazi, M ;

Kivekäs, R ;

Klinga, M ;

Moreno, JM .

CHEMICAL COMMUNICATIONS, 1998, (10) :1071-1072

[7] FERROMAGNETISM IN DECAMETHYLCHROMOCENIUM TETRACYANOETHYLENIDE - CONFIGURATION MIXING DOES NOT EXPLAIN FERROMAGNETIC SPIN COUPLING IN METALLOCENIUM CHARGE-TRANSFER SALTS [J].

EICHHORN, DM ;

SKEE, DC ;

BRODERICK, WE ;

HOFFMAN, BM .

INORGANIC CHEMISTRY, 1993, 32 (04) :491-492

[8] A chromium(III) nickel(II) cyanide-bridged ferromagnetic layered structure with corrugated sheets [J].

Ferlay, S ;

Mallah, T ;

Vaissermann, J ;

Bartolome, F ;

Veillet, P ;

Verdaguer, M .

CHEMICAL COMMUNICATIONS, 1996, (21) :2481-2482

[9]

Figgis B. N., 1964, PROGR INORGANIC CHEM, DOI 10.1016/B978-0-08-012210-6.50064-8

[10] Crystal structure and magnetic properties of an infinite chainlike and a tetranuclear bimetallic copper(II)-chromium(III) complex with bridging cyanide ions [J].

Fu, DG ;

Chen, J ;

Tan, XS ;

Li, JJ ;

Zhang, SW ;

Zheng, PJ ;

Tang, WX .

INORGANIC CHEMISTRY, 1997, 36 (02) :220-225

← 1 2 3 4 →