Recent advances of spin crossover research

被引:76
作者
Gütlich, P
van Koningsbruggen, PJ
Renz, F
机构
[1] Johannes Gutenberg Univ Mainz, Inst Anorgan Chem & Analyt Chem, D-55099 Mainz, Germany
[2] Univ Groningen, Stratingh Inst Chem & Chem Engn, NL-9747 AG Groningen, Netherlands
来源
OPTICAL SPECTRA AND CHEMICAL BONDING IN TRANSITION METAL COMPLEXES | 2004年 / 107卷
关键词
spin crossover; physical properties; cooperativity; pressure; light effects;
D O I
10.1007/b96897
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Thermal spin transition (spin crossover), one of the most fascinating dynamic electronic structure phenomena occurring in coordination compounds of third row transition metal ions, mostly of iron(II), iron(III) and cobalt(II) with critical ligand field strengths competing with the spin pairing energy, has attracted increasing attention by many research groups. One of the reasons is the promising potential for practical applications. In this chapter we intend to cover essential recent work, primarily accomplished within the European research network on "Thermal and Optical Switching of Molecular Spin States (TOSS)". New spin crossover compounds and their thermal spin transition behaviour, also under applied pressure, novel effects observed by irradiation and magnetic field, will be discussed. Progress in theoretical treatments of spin crossover phenomena, particularly cooperativity, will be briefly outlined. The chapter concludes with a summary of research highlights published by the partner laboratories of the TMR network TOSS.
引用
收藏
页码:27 / 75
页数:49
相关论文
共 235 条
  • [1] MOSSBAUER RELAXATION SPECTRA IN ARBITRARILY ORDERED ABSORBERS - LINE-SHAPE ANALYSIS FOR AN IRON(II) SPIN-CROSSOVER COMPLEX IN THE PRESENCE OF TEXTURE
    ADLER, P
    POGANIUCH, P
    SPIERING, H
    [J]. HYPERFINE INTERACTIONS, 1989, 52 (01): : 47 - 63
  • [2] THERMODYNAMICS AND KINETICS OF SPIN STATE CONVERSION PROCESSES STUDIED BY PRESSURE DEPENDENT MOSSBAUER-SPECTROSCOPY
    ADLER, P
    SPIERING, H
    GUTLICH, P
    [J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1989, 50 (06) : 587 - 597
  • [3] LIGHT-INDUCED EXCITED SPIN STATE TRAPPING (LIESST) FOR FE(II) COMPLEXES - INFRARED STUDIES AT CA 10-298-K
    BALDENIUS, KU
    CAMPEN, AK
    HOHNK, HD
    REST, AJ
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 1987, 157 (1-3) : 295 - 299
  • [4] COMPARATIVE-STUDY OF THE PRESSURE EFFECT ON CRITICAL PARAMETERS OF GDBA2CU4O8 AND YBA2CU4O8
    BARAN, M
    DYAKONOV, V
    GLADCZUK, L
    LEVCHENKO, G
    PIECHOTA, S
    SZYMCZAK, H
    [J]. PHYSICA C, 1995, 241 (3-4): : 383 - 388
  • [5] LOW-SPIN HIGH-SPIN TRANSITIONS IN TRANSITION-METAL-ION COMPOUNDS
    BARI, RA
    SIVARDIERE, J
    [J]. PHYSICAL REVIEW B-SOLID STATE, 1972, 5 (11): : 4466 - +
  • [6] ELECTRONIC AND SPATIAL STRUCTURE OF SPIN TRANSITION IRON(II) TRIS(4-AMINO-1,2,4-TRIAZOLE) NITRATE AND PERCHLORATE COMPLEXES
    BAUSK, NV
    ERENBURG, SB
    MAZALOV, LN
    LAVRENOVA, LG
    IKORSKII, VN
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 1994, 35 (04) : 509 - 516
  • [7] First ligand-driven light-induced spin change at room temperature in a transition-metal molecular compound
    Boillot, ML
    Chantraine, S
    Zarembowitch, J
    Lallemand, JY
    Prunet, J
    [J]. NEW JOURNAL OF CHEMISTRY, 1999, 23 (02) : 179 - 183
  • [8] Pressure-induced spin-state crossovers at room temperature in iron(II) complexes:: comparative analysis;: a XANES investigation of some new transitions
    Boillot, ML
    Zarembowitch, J
    Itié, JP
    Polian, A
    Bourdet, E
    Haasnoot, JG
    [J]. NEW JOURNAL OF CHEMISTRY, 2002, 26 (03) : 313 - 322
  • [9] Boillot ML, 1999, COORDIN CHEM REV, V190, P47
  • [10] Ligand-driven light-induced spin change in transition-metal complexes: Selection of an appropriate system and first evidence of the effect, in Fe-II(4-styrylpyridine)(4)(NCBPh(3))(2)
    Boillot, ML
    Roux, C
    Audiere, JP
    Dausse, A
    Zarembowitch, J
    [J]. INORGANIC CHEMISTRY, 1996, 35 (13) : 3975 - 3980