Relaxation dynamics in the presence of unequally spaced attractors along the reaction coordinate

被引:4
作者
Despa, F [1 ]
Berry, RS [1 ]
机构
[1] Univ Chicago, Dept Chem, Chicago, IL 60637 USA
关键词
D O I
10.1007/s100530170059
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
We show how reaction coordinate path lengths affect the relaxation efficiency of a complex system. To this purpose, we consider the metric contributions to the transition rates. These metric contributions contain information about the system's change of geometry at the barrier crossing and, therefore, are directly related, differentially, to the path lengths. The results of this work can enrich the accuracy with which we describe how complex systems relax to preferential structures.
引用
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页码:55 / 58
页数:4
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