Polymerisation of ethene by the novel titanium complex [Ti(Me(3)SiNCH(2)CH(2)NSiMe(3))Cl-2]; A metallocene analogue

被引：76

作者：

Tinkler, S

Deeth, RJ

Duncalf, DJ

McCamley, A

机构：

[1] Department of Chemistry, University of Warwick, Coventry

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 23期

关键词：

D O I：

10.1039/cc9960002623

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of the trimethylsilylated diamine ligand (Me(3)-Si)NHCH2CH2NH(SiMe(3)) with titanium(IV) precursors affords the novel distorted-tetrahedral complex [Ti(Me(3)-SiNCH(2)CH(2)NSiMe(3))Cl-2] which, when activated by methylaluminoxane, is an active ethene polymerisation catalyst.

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页码：2623 / 2624

页数：2

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