'Chicken-coop' network assembled by hydrogen bonds with bridging nitrate ions.: Crystal structure of bis(4, 4′-bipyridinium) diaquatetraisothiocyanatonickellate(II) dinitrate

被引：23

作者：

Chen, HJ

Tong, ML

Chen, XM ^{[1
]}

机构：

[1] Zhongshan Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China

[2] Jinan Univ, Dept Chem, Guangzhou 510632, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 02期

基金：

中国国家自然科学基金;

关键词：

crystal engineering; hydrogen bonds; nickel thiocyanate; 4,4 '-bipyridinium;

D O I：

10.1016/S1387-7003(00)00210-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The two-dimensional hydrogen-bonded honeycomb networks formulated as (4,4'-H(2)bipy)(2)[Ni(NCs)(4)(H2O)(2)](NO3)(2) (4 4'-H(2)bipy = 4,4'-bipyridinium) with R-12(10)(64) rings and ca. 24 x 20 Angstrom internal dimensions are triply interwoven to generate two-dimensional 'chicken-coop' sheets, featuring unusual hydrogen bonds involving the NO3- groups. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：76 / 78

页数：3

共 31 条

[1]

Aakeröy CB, 1999, ANGEW CHEM INT EDIT, V38, P1815, DOI 10.1002/(SICI)1521-3773(19990614)38:12<1815::AID-ANIE1815>3.0.CO

[2]

2-S

[3] CRYSTAL-STRUCTURE AND ANION-DEPENDENT VARIATIONS IN THE VIBRATIONAL-SPECTRA OF 4,4'-BIPYRIDINIUM CATIONS [J].