New conducting polymers: Preparation and spectroscopic properties of zinc-porphyrin and anthraquinone-coated electrodes

被引:14
作者
Allietta, N
Pansu, R
BiedCharreton, C
Albin, V
Bedioui, F
Devynck, J
机构
[1] ECOLE NORMALE SUPER,URA 1906 CNRS,F-94235 CACHAN,FRANCE
[2] ECOLE NATL SUPER CHIM,URA 216 CNRS,LAB ELECTROCHIM & CHIM ANALYT,F-75231 PARIS 05,FRANCE
关键词
zinc porphyrin; anthraquinone; electrodes; spectroscopy;
D O I
10.1016/S0379-6779(96)03741-1
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This study concerns some aspects of the electrochemical design and characterization of zinc porphyrins and anthraquinone-based polymers. The electro-formation of the films on the electrode surface is achieved by cyclic voltammetry in organic solvents such as acetonitrile. Film deposition is based on the electrochemical oxidative polymerization of the pyrrole-substituted phenyl groups attached on the porphyrin or anthraquinone molecules. The redox characteristics of the polymer films are studied by cyclic voltammetry and spectrophotometry, and are compared to those of the starting monomers. Attempts to find a correlation between the composition of the conducting polymers and the electrochemical and spectroscopic properties of the zinc porphyrin are discussed.
引用
收藏
页码:205 / 210
页数:6
相关论文
共 16 条
[1]   ELECTROCHEMICAL PREPARATION OF ANTHRAQUINONE AND ZINC PORPHYRIN COATED ELECTRODES - REDOX ACTIVITY AND FILM STABILITY [J].
BALASUBRAMANIAM, E ;
RAMACHANDRAIAH, G ;
NATARAJAN, P ;
BIEDCHARRETON, C ;
DEVYNCK, J ;
BEDIOUI, F .
JOURNAL OF MATERIALS CHEMISTRY, 1995, 5 (04) :625-629
[2]   PHOTOELECTROCHEMICAL STUDIES OF METALLOPORPHYRINS [J].
BASU, J ;
ROHATGIMUKHERJEE, KK .
PHOTOCHEMISTRY AND PHOTOBIOLOGY, 1988, 48 (04) :417-422
[3]  
BASU J, 1991, SOL ENERG MATER, V21, P17
[4]   IMMOBILIZATION OF METALLOPORPHYRINS IN ELECTROPOLYMERIZED FILMS - DESIGN AND APPLICATIONS [J].
BEDIOUI, F ;
DEVYNCK, J ;
BIEDCHARRETON, C .
ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (01) :30-36
[5]  
BEDIOUI F, 1985, B SOC CHIM FR, V5, P679
[6]   POLY(PYRROLE-METALLOTETRAPHENYLPORPHYRIN)-MODIFIED ELECTRODES .2. [J].
DERONZIER, A ;
DEVAUX, R ;
LIMOSIN, D ;
LATOUR, JM .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1992, 324 (1-2) :325-337
[7]   THE PREPARATION OF PYRROLES FROM FURANS [J].
ELMING, N ;
CLAUSONKAAS, N .
ACTA CHEMICA SCANDINAVICA, 1952, 6 (06) :867-874
[8]  
FURHRHOP JH, 1992, J AM CHEM SOC, V114, P4159
[9]  
FURHRHOP JH, 1990, J AM CHEM SOC, V112, P2827
[10]  
FURHRHOP JH, 1993, J AM CHEM SOC, V115, P11036