Effective synthesis of 1,3-diselenole-2-selone-4,5-diselenolate (dsis) and its utilization for the synthesis of selenocycle-fused tetraselenafulvalene (TSF) derivatives

被引:19
作者
Kodani, M
Takimiya, K [1 ]
Aso, Y
Otsubo, T
Nakayashiki, T
Misaki, Y
机构
[1] Hiroshima Univ, Fac Engn, Dept Appl Chem, Higashihiroshima 7398527, Japan
[2] Kyoto Univ, Grad Sch Engn, Dept Mol Engn, Sakyo Ku, Kyoto 6068501, Japan
来源
SYNTHESIS-STUTTGART | 2001年 / 11期
关键词
lithiation; diselenolate ligands; protecting groups; ring-closure reaction; selenium-containing heterocycles;
D O I
10.1055/s-2001-16755
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A facile and effective synthetic procedure for 1,3-diselenole-2-selone-4.5-diselenolate (dsis, 2) has been established. The utilization of 2 for the synthesis of selenocycle-fused tetraselenafulvalene derivatives is also reported.
引用
收藏
页码:1614 / 1618
页数:5
相关论文
共 14 条