Spherical polyphenylene dendrimers via Diels-Alder reactions:: the first example of an A4B building block in dendrimer chemistry

被引：85

作者：

Morgenroth, F ^{[1
]}

Berresheim, AJ ^{[1
]}

Wagner, M ^{[1
]}

Müllen, K ^{[1
]}

机构：

[1] Max Planck Inst Polymerforsch, D-55128 Mainz, Germany

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 10期

关键词：

D O I：

10.1039/a801395k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The [2+4]cycloaddition of the novel A(4)B building block 2,3,4,5-tetrakis(4-triisopropylsilylethynylphenyl)-cyclopenta-2,4-dienone 3 with 3,3',5,5'-tetraethynylbiphenyl 1 allows the rapid synthesis of a spherical polyphenylene nanoparticle with 102 benzene rings.

引用

页码：1139 / 1140

页数：2

共 13 条

[1]

DEGENNES PG, 1983, J PHYS LETT-PARIS, V44, pL351, DOI 10.1051/jphyslet:01983004409035100

[2]

FRECHET JMJ, 1996, COMPREHENSIVE POLY S, V2, pS70

[3] WATER-SOLUBLE HYPERBRANCHED POLYPHENYLENE - A UNIMOLECULAR MICELLE [J].

KIM, YH ;

WEBSTER, OW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (11) :4592-4593

[4] CONCEPTS OF TRAPPING TOPOLOGICALLY BY SHELL MOLECULES [J].

MACIEJEWSKI, M .

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1982, A17 (04) :689-703

[5] SYNTHESIS AND CHARACTERIZATION OF A SERIES OF MONODISPERSE, 1,3,5-PHENYLENE-BASED HYDROCARBON DENDRIMERS INCLUDING C276H186 AND THEIR FLUORINATED ANALOGS [J].

MILLER, TM ;

NEENAN, TX ;

ZAYAS, R ;

BAIR, HE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (03) :1018-1025

[6] Dendritic and hyperbranched polyphenylenes via a simple Diels-Alder route [J].

Morgenroth, F ;

Mullen, K .

TETRAHEDRON, 1997, 53 (45) :15349-15366

[7] Nanosized polyphenylene dendrimers based upon pentaphenylbenzene units [J].

Morgenroth, F ;

Kubel, C ;

Mullen, K .

JOURNAL OF MATERIALS CHEMISTRY, 1997, 7 (07) :1207-1211

[8] Polyphenylene dendrimers: From three-dimensional to two-dimensional structures [J].

Morgenroth, F ;

Reuther, E ;

Mullen, K .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (06) :631-634

[9]

MORGENROTH F, 1997, ANGEW CHEM, V109, P647

[10]

Newkome G.R., 1996, DENDRITIC MOL

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