Microwave-hydrothermal synthesis and hyperfine characterization of praseodymium-doped nanometric zirconia powders

被引：33

作者：

Bondioli, F ^{[1
]}

Leonelli, C

Manfredini, T

Ferrari, AM

Caracoche, MC

Rivas, PC

Rodríguez, AM

机构：

[1] Univ Modena, Dipartimento Ingn Mat & Ambiente, I-41100 Modena, Italy

[2] Univ Modena, Dipartimento Sci & Metodi Ingn, I-42100 Reggio Emilia, Italy

[3] Natl Univ La Plata, Dept Fis, RA-1900 La Plata, Argentina

来源：

JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 2005年 / 88卷 / 03期

关键词：

D O I：

10.1111/j.1551-2916.2005.00093.x

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

This work focuses on the microwave-assisted hydrothermal synthesis of praseodymium-doped zirconia and on the subsequent evaluation of the effect of synthesis conditions on powder properties. Pure and 10 mol% Pr-doped zirconia samples have been analyzed by X-ray diffraction (XRD) and the perturbed angular correlations hyperfine technique, which probes the nearest environments of zirconium ions. At atomic scale, as determined from perturbed angular correlation data, the XRD amorphous fraction of the as-obtained powders exhibits a tetragonal-like structure. The pure powder becomes partially stabilized and the doped powder is a substitutional solid solution of praseodymium in tetragonal zirconia.

引用

页码：633 / 638

页数：6

共 30 条

[1] Microwave-hydrothermal synthesis of nanocrystalline zirconia powders [J].

Bondioli, F ;

Ferrari, AM ;

Leonelli, C ;

Siligardi, C ;

Pellacani, GC .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2001, 84 (11) :2728-2730

[2]

BONDIOLI F, 2003, IN PRESS ADV MICROWA

[3] Structural changes of rare-earth-doped, nanostructured zirconia solid solution [J].

Boulc'h, F ;

Djurado, E .

SOLID STATE IONICS, 2003, 157 (1-4) :335-340

[4] Phase structure and thermal evolution in coating films and powders obtained by sol-gel process .2. ZrO2-2.5 mole % Y2O3 [J].

Caruso, R ;

Benavidez, E ;

deSanctis, O ;

Caracoche, MC ;

Rivas, PC ;

Cervera, M ;

Caneiro, A ;

Serquis, A .

JOURNAL OF MATERIALS RESEARCH, 1997, 12 (10) :2594-2601

[5] Solid state NMR and X-ray studies of the structural evolution of nanocrystalline zirconia [J].

Chadwick, AV ;

Mountjoy, G ;

Nield, VM ;

Poplett, IJF ;

Smith, ME ;

Strange, JH ;

Tucker, MG .

CHEMISTRY OF MATERIALS, 2001, 13 (04) :1219-1229

[6] Role of praseodymium on zirconia phases stabilization [J].

Corradi, AB ;

Bondioli, F ;

Ferrari, AM .

CHEMISTRY OF MATERIALS, 2001, 13 (12) :4550-4554

[7]

CULLIRY BD, 1997, ELEMENTS XRAY DIFFRA

[8] Dehydroxylation and the crystalline phases in sol-gel zirconia [J].

Gomez, R ;

Lopez, T ;

Bokhimi, X ;

Munoz, E ;

Boldu, JL ;

Novaro, O .

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 1998, 11 (03) :309-319

[9] STRUCTURES OF THE ZRO2 POLYMORPHS AT ROOM-TEMPERATURE BY HIGH-RESOLUTION NEUTRON POWDER DIFFRACTION [J].

HOWARD, CJ ;

HILL, RJ ;

REICHERT, BE .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 1988, 44 :116-120

[10]

*INT CTR DIFFR DAT, 1995, 421164 INT CTR DIFFR

← 1 2 3 →