Structure and magnetic properties of Mn-doped ZnO nanoparticles

被引:106
作者
Luo, J
Liang, JK
Liu, QL
Liu, FS
Zhang, Y
Sun, BJ
Rao, GH
机构
[1] Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100080, Peoples R China
[2] Acad Sinica, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
关键词
D O I
10.1063/1.1873058
中图分类号
O59 [应用物理学];
学科分类号
摘要
We report the crystal structure and magnetic properties of the Zn1-xMnxO compounds synthesized by a combustion method. The Zn1-xMnxO compounds with x=0-0.1 crystallize in the wurtzite ZnO structure. The lattice parameters a and c of Zn1-xMnxO increase linearly with the Mn content, indicating that Mn2+ ions substitute for Zn2+ ions. Scanning electron microscopy shows that the average particle radius of Zn0.95Mn0.05O is about 40 nm. From the Curie-Weiss behavior of susceptibility at high temperature, it was found that the Mn-Mn interaction is dominated by antiferromagnetic coupling with effective nearest-neighbor exchange constant J about -32 K and the large negative value of the Curie-Weiss temperature. (C) 2005 American Institute of Physics.
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页数:3
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