Self-assembled polymers of silver(I) with a chiral diphosphine ligand

被引:22
作者
Nasser, Nasser [1 ]
Puddephatt, Richard J. [1 ]
机构
[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
COORDINATION POLYMERS; COMPLEXES; ALDOL;
D O I
10.1039/c0cc05411a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Silver(I) salts, AgX, form self-assembled polymers with the chiral diphosphine ligand R, R-trans-C6H10(NHCO-2-C6H4PPh2)(2), 1, of formula {Ag2X2(mu-1)}(n) and ring-opening polymerization of the trans chelate complex [Ag(1)]X has given the helical polymer [{Ag(mu-1)}(n)]X-n, when X = CF3SO3.
引用
收藏
页码:2808 / 2810
页数:3
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