Synthesis of stable monomeric iridium(0) and iridium(-1) complexes

被引:17
作者
Boulmaaz, S
Mlakar, M
Loss, S
Schönberg, H
Deblon, S
Wörle, M
Nesper, R
Grützmacher, H
机构
[1] ETH Zentrum, Anorgan Chem Lab, CH-8092 Zurich, Switzerland
[2] Ctr Marine Res Zagreb, Rudjer Boskovic Inst, Zagreb 10001, Croatia
关键词
D O I
10.1039/a807804a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Using the tropp(Ph) ligand 1, stable monomeric d(8)-Ir+I, d(9)-Ir-0 and d(10)-Ir-I complexes could be isolated and structurally characterized; in all complexes, the metal centre lies within a coordination sphere intermediate between a square plane and a tetrahedron.
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页码:2623 / 2624
页数:2
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