Rheological properties of particle suspensions in a polymeric liquid

被引:26
作者
Choi, HJ [1 ]
Vinay, SJ
Jhon, MS
机构
[1] Inha Univ, Dept Polymer Sci & Engn, Inchon 402751, South Korea
[2] Carnegie Mellon Univ, Dept Chem Engn, Pittsburgh, PA 15213 USA
关键词
Boger fluid; particle suspension; rheological property;
D O I
10.1016/S0032-3861(98)00498-4
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The rheological characteristics of a particle-suspended Boger fluid are reported. Non-shear thinning, highly elastic polymer solutions were obtained from a mixture of high-molecular-weight polyisobutylene (PIB) and low-molecular-weight polybutene (PB). Kaolinite was chosen as the suspended particles. The shear viscosity and first normal stress difference of the kaolinite-suspended PIB/PB solution exhibit characteristics similar to those of Boger fluids. In contrast to polymer melts with nearly spherical particles, the elasticity of this system increases with the addition of particles, and a qualitative interpretation based on PB (the solvent) as a 'shielding' agent is given. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:2869 / 2872
页数:4
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