Self-assembly preparation, structure and magnetic studies of a novel dinuclear copper(II) complex:: [Cu2(μ-OH)(μ-OAc)(μ-L)][BF4]2 [L = bis-1,3-(cis,cis-1,3,5-triaminocyclohexane)xylylidiene]

被引：35

作者：

Boxwell, CJ

Bhalla, R

Cronin, L

Turner, SS

Walton, PH ^{[1
]}

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

[2] UCL Royal Inst Great Britain, London W1X 4BS, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 15期

关键词：

D O I：

10.1039/a803796e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of a novel dinuclear copper(II) complex, with the bridging ligand bis-1,3-(cis,cis-1,3,5-triaminocyclohexane)xylylidiene has been obtained; the complex was prepared using a single-pot reaction of copper(II) salts, isophthalaldehyde and cis,cis-1,3,5-triaminocyclohexane.

引用

收藏

页码：2449 / 2450

页数：2

相关论文

共 20 条

[1] ANOMALOUS PARAMAGNETISM OF COPPER ACETATE [J].

BLEANEY, B ;

BOWERS, KD .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1952, 214 (1119) :451-465

[2] LIPOPHILIC HEXADENTATE ALUMINUM COMPLEXES OF NEW PHENOLATE-DERIVATIZED CYCLOHEXANETRIAMINE LIGANDS AND THEIR EFFECT ON THE PEPTIDE-TRANSPORT SYSTEM (PTS-1) [J].

BOLLINGER, JE ;

MAGUE, JT ;

BANKS, WA ;

KASTIN, AJ ;

ROUNDHILL, DM .

INORGANIC CHEMISTRY, 1995, 34 (08) :2143-2152

[3] ZINC-COMPLEXES OF CYCLOHEXANE TRIAMINE LIGANDS [J].

BRAND, U ;

VAHRENKAMP, H .

INORGANICA CHIMICA ACTA, 1992, 198 :663-669

[4] Moderately strong antiferromagnetic exchange coupling in a dinuclear complex containing a mu-hydroxo-mu-carboxylatodicopper(II) core [J].

Burger, KS ;

Chaudhuri, P ;

Wieghardt, K .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (02) :247-248

[5] PREPARATION AND PROPERTIES OF THE TRIPLY BRIDGED, FERROMAGNETICALLY COUPLED DINUCLEAR COPPER(II) COMPLEXES [CU2(OAC)3(BPY)2](CLO4) AND [CU2(OH)(H2O)(OAC)(BPY)2](CLO4)2 [J].

CHRISTOU, G ;

PERLEPES, SP ;

LIBBY, E ;

FOLTING, K ;

HUFFMAN, JC ;

WEBB, RJ ;

HENDRICKSON, DN .

INORGANIC CHEMISTRY, 1990, 29 (19) :3657-3666

[6]

CORNIN L, 1996, J CHEM SOC DA, P3337

[7] Synthesis and single crystal X-ray structure of a novel trinuclear copper(II) methoxide complex [J].

Cronin, L ;

Walton, PH .

INORGANICA CHIMICA ACTA, 1998, 269 (02) :241-245

[8] Syntheses and single-crystal X-ray structures of a series of monosubstituted cis,cis-1,3,5-triaminocyclohexane-based complexes [J].

Cronin, L ;

Greener, B ;

Foxon, SP ;

Heath, SL ;

Walton, PH .

INORGANIC CHEMISTRY, 1997, 36 (12) :2594-2600

[9] The United Kingdom Chemical Database Service [J].

Fletcher, DA ;

McMeeking, RF ;

Parkin, D .

JOURNAL OF CHEMICAL INFORMATION AND COMPUTER SCIENCES, 1996, 36 (04) :746-749

[10]

FUJII Y, 1995, CHEM LETT, P307