Changes in electronic couplings of mixed-valence systems due to through-space intramolecular interactions

被引:21
作者
Figueira-Duarte, Teresa M.
Lloveras, Vega
Vidal-Gancedo, Jose
Gegout, Aline
Delavaux-Nicot, Beatrice
Welter, Richard
Veciana, Jaume
Rovira, Concepcio
Nierengarten, Jean-Francois
机构
[1] Inst Ciencia Mat Barcelona, Cerdanyola Del Valles 08193, Spain
[2] CNRS, Chim Coordinat Lab, Grp Chim Fullerenes & Syst Conjugues, F-31077 Toulouse 4, France
[3] Univ Strasbourg 1, Lab DECOMET, F-67000 Strasbourg, France
关键词
D O I
10.1039/b707522g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The strength of the electronic interactions between the two redox moieties in fullerene-substituted mixed-valence bis(ferrocenylethynyl) ethene derivatives is modulated by the throughspace intramolecular electronic interactions of C-60 with the bridging conjugated system.
引用
收藏
页码:4345 / 4347
页数:3
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