Conformations of linear chains. Systematics and suggestions for nomenclature

被引：133

作者：

Michl, J

West, R

机构：

[1] Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA

[2] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2000年 / 33卷 / 12期

关键词：

D O I：

10.1021/ar0001057

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

There are six categories of calculated favored dihedral angles in linear MnX2n+2 chains. The Prelog-Klyne nomenclature is not helpful for classifying them, and we propose the following labels and symbols: A, anti, reserved for torsional angles within a few degrees of 180 degrees; T, transoid, omega similar or equal to 165 degrees; D, deviant, omega similar or equal to 150 degrees; O, ortho, omega similar or equal to 90 degrees; G, gauche, omega similar or equal to 60 degrees; C, cisoid, omega similar or equal to 40 degrees. With the exception of C, all of these categories have been observed in alkanes, perfluoroalkanes, or oligosilanes.

引用

页码：821 / 823

页数：3

共 37 条

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