Determination of the stoichiometry of CuxInySez by total-reflection XRF

被引：21

作者：

Fernández-Ruiz, R ^{[1
]}

Cabañero, JP

Hernández, E

León, M

机构：

[1] Univ Autonoma Madrid, Serv Interdepartamental Invest, Fac Ciencias, E-28049 Madrid, Spain

[2] Univ Zulia, Dept Fis, Fac Ciencias Expt, Maracaibo 4011, Venezuela

[3] Univ Autonoma Madrid, Fac Ciencias, Dept Fis Aplicada, E-28049 Madrid, Spain

来源：

ANALYST | 2001年 / 126卷 / 10期

关键词：

D O I：

10.1039/b104466b

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A rapid and accurate total-re flection XRF method was developed in order to determine the absolute stoichiometry of ternary compounds of the type Cu:In:Se. The method was used to determine the composition of the synthesised compounds CuAInySez(CIS). Three compounds were synthesised with different atomic proportions x:y:z; 1:3:5, 2:4:7 and the no stoichiometric phase 1:2.5:4.75. The results obtained showed a systematic deficiency of In and an increment of Se with respect to the stoichiometric formula.

引用

页码：1797 / 1799

页数：3

共 8 条

[1] Analysis of archaeological ceramics by TXRF and contrasted with NAA [J].

García-Heras, M ;

Fernández-Ruiz, R ;

Tornero, JD .

JOURNAL OF ARCHAEOLOGICAL SCIENCE, 1997, 24 (11) :1003-1014

[2]

Hedstrom J., 1993, P 23 IEEE PHOT SPEC, P364

[3]

KESSLER J, 1993, P 23 IEEE PHOT SPEC, P549

[4] TOTAL REFLECTION X-RAY SPECTROMETRY - METHOD AND APPLICATIONS [J].

PRANGE, A .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 1989, 44 (05) :437-452

[5] CHALCOPYRITE DEFECT CHALCOPYRITE HETEROJUNCTIONS ON THE BASIS OF CUINSE2 [J].

SCHMID, D ;

RUCKH, M ;

GRUNWALD, F ;

SCHOCK, HW .

JOURNAL OF APPLIED PHYSICS, 1993, 73 (06) :2902-2909

[6]

TOLG G, 1993, SPECTROCHIM ACTA B, V48, P111, DOI 10.1016/0584-8547(93)80015-M

[7]

TURTLE JR, 1991, SOL CELLS, V30, P21

[8]

ZIAO HZ, 1994, J APPL PHYS, V76, P1503

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