Glutamic acid dendrimers attached to a central ferrocene core: Synthesis and properties

被引：27

作者：

Appoh, FE ^{[1
]}

Thomas, DS ^{[1
]}

Kraatz, HB ^{[1
]}

机构：

[1] Univ Saskatchewan, Dept Chem, Saskatoon, SK S7N 5C9, Canada

来源：

MACROMOLECULES | 2005年 / 38卷 / 18期

关键词：

D O I：

10.1021/ma050531d

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The first synthesis of a series of glutamic acid based dendrimers having a central ferrocene core is described. The materials were fully characterized spectroscopically and display strong intramolecular H-bonding. This H-bonding can be disrupted with DMSO. The redox properties of the core are attenuated by the increase in the peptide dendritic sphere. But even at generation 6, there is communication between the exterior and the redox core.

引用

页码：7562 / 7570

页数：9

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