Reactions of N-nitramines and their trimethylsilyl derivatives with N,N-bis(trimethylsilyloxy)enamines

被引：6

作者：

Ioffe, SL ^{[1
]}

Makarenkova, LM ^{[1
]}

Strelenko, YA ^{[1
]}

Bliznets, IV ^{[1
]}

Tartakovsky, VA ^{[1
]}

机构：

[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 117913, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1998年 / 47卷 / 10期

基金：

俄罗斯基础研究基金会;

关键词：

nitramines; silylation; N; C-cross-coupling; N-bis(trimethylsilyloxy)enamines;

D O I：

10.1007/BF02494513

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Trimethylsilyl derivatives of methyl- and ethylnitramine react as N-centered nucleophiles with 2-N,N-bis(trimethylsilyloxy)aminopropene to give trimethylsilyl derivatives of hitherto unknown alpha-(N-nitro)alkylamino-substituted acetone oximes. As an ambident nucleophile, nonsubstituted methylnitramine reacts with the same enamine to give both a product of N,C-cross-coupling and a product of O,C-cross-coupling, viz., N'-methyl-N-[(2-trimethylsilyloxyimino)propoxy]diazene N-oxide.

引用

页码：1989 / 1991

页数：3