Dynamic equilibration of η1-carbene and η2-alkyne moieties within an alkynylcarbene dimanganese complex

被引：15

作者：

Ortin, Y ^{[1
]}

Coppel, Y ^{[1
]}

Lugan, N ^{[1
]}

Mathieu, R ^{[1
]}

McGlinchey, MJ ^{[1
]}

机构：

[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse 4, France

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 17期

关键词：

D O I：

10.1039/b104712b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The coordination of an additional [CP(CO)(2)Mn] fragment to the alkyne linkage of an alkynylcarbene complex of the type CP(CO)(2)Mn-C(R')C=CR" yields a highly fluxional molecule, in which the [eta (1)-carbene] and [eta (2)-alkyne] moieties are seen to exchange rapidly on the NMR time scale.

引用

收藏

页码：1690 / 1691

页数：2

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