A single-crystal-to-single-crystal transformation mediated by argentophilic forces converts a finite metal complex into an infinite coordination network

被引：257

作者：

Chu, QL ^{[1
]}

Swenson, DC ^{[1
]}

MacGillivray, LR ^{[1
]}

机构：

[1] Univ Iowa, Dept Chem, Iowa City, IA 52242 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 23期

关键词：

2+2] photodimerization; self-assembly; silver; single-crystal reactions; topochemistry;

D O I：

10.1002/anie.200500400

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Reactions in crystals: Interactions between AgI ions are used to preorganize olefins for a regiocontrolled single-crystal-to-single-crystal (SCSC) [2+2] photodimerization that results in a quantitative conversion of a finite dinuclear complex into a one-dimensional coordination network (see scheme). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：3569 / 3572

页数：4

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