Triple C-H activation of a cycloalkyl ketone using an osmium-hexahydride complex

被引：73

作者：

Barrio, P ^{[1
]}

Castarlenas, R ^{[1
]}

Esteruelas, MA ^{[1
]}

Oñate, E ^{[1
]}

机构：

[1] Univ Zaragoza, Inst Ciencia Mat Aragon, Dept Quim Inorgan, CSIC, Zaragoza 50009, Spain

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 12期

关键词：

D O I：

10.1021/om010112e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hexahydride OsH6((PPr3)-Pr-i)(2) reacts with cyclohexylmethyl ketone to give the trihydride OsH3-{C6H8C(O)CH3)((PPr3)-Pr-i)(2), which has been characterized by X-ray diffraction analysis. In solution, the hydride ligands of this complex undergo two different thermally activated exchange processes. Two of them also show weak quantum exchange coupling.

引用

页码：2635 / 2638

页数：4

共 25 条

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