An easy synthetic route to heteroleptic samarium monoalkoxides for ring-opening polymerization initiators.: Molecular structures of [(C5Hi-Pr4)SmI(THF)2]2, SMI2Ot-Bu(THF)4, and (C4Me4P)2SmOt-Bu(THF)

被引：31

作者：

Barbier-Baudry, D

Heiner, S

Kubicki, MM

Vigier, E

Visseaux, M

Hafid, A

机构：

[1] UMR 5632, LSEO, F-21078 Dijon, France

[2] Fac Sci & Tech, Dept Chim & Environm, Beni Mellal, Morocco

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 20期

关键词：

D O I：

10.1021/om010423p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Samarium(III) monoalkoxides bearing two, one, or no cyclopentadienyl type spectator ligands are easily synthesized by monoelectronic oxidation with tert-butylperoxide of the corresponding samarium(II) precursors. These monoalkoxides are single-site initiators for ring-opening polymerization.

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页码：4207 / 4210

页数：4

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