Vanadium complexes containing the 2,4,6-tris(trifluoromethyl)phenyl ('fluoromes') ligand

被引：21

作者：

Gibson, VC

Redshaw, C

Sequeira, LJ

Dillon, KB

Clegg, W

Elsegood, MRJ

机构：

[1] UNIV DURHAM,DEPT CHEM,DURHAM DH1 3LE,ENGLAND

[2] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 18期

关键词：

D O I：

10.1039/cc9960002151

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of [VCl3(thf)(3)] (thf = tetrahydrofuran) with Li[C6H2(CF3)(3)-2,4,6] affords the first early transition-metal complexes containing the sigma-bonded fluoromes ligand; the molecular structures of [V{C6H2(CF3)(3)-2,4,6}Cl-2(thf)] 1 and [V{c(6)H(2)(CF3)(3)-2,4,6}3OLi(thf)(3)] 2 are described.

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页码：2151 / 2152

页数：2

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