Bottom up synthesis that does not start at the bottom: Quadruple covalent cross-linking of nanoscale faceted polyhedra

被引:188
作者
Perry, John J.
Kravtsov, Victor Ch.
McManus, Gregory J.
Zaworotko, Michael J.
机构
[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA
[2] Moldavian Acad Sci, Inst Appl Phys, MD-2028 Kishinev, Moldova
关键词
D O I
10.1021/ja0734952
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel 3D metal-organic coordination polymer constructed from hollow, spherical, nanometer-sized molecular faceted polyhedra and a flexible tetracarboxylate ligand designed to simultaneously assemble and cross-link these nanoballs in situ has been synthesized and structurally characterized. The crystal structure involves 2-fold interpenetration with each framework exhibiting pores of dimensions which vary from less than 1 nm to just over 2.5 nm.
引用
收藏
页码:10076 / +
页数:3
相关论文
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