Bottom up synthesis that does not start at the bottom: Quadruple covalent cross-linking of nanoscale faceted polyhedra

被引：188

作者：

Perry, John J.

Kravtsov, Victor Ch.

McManus, Gregory J.

Zaworotko, Michael J.

机构：

[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

[2] Moldavian Acad Sci, Inst Appl Phys, MD-2028 Kishinev, Moldova

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 33期

关键词：

D O I：

10.1021/ja0734952

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel 3D metal-organic coordination polymer constructed from hollow, spherical, nanometer-sized molecular faceted polyhedra and a flexible tetracarboxylate ligand designed to simultaneously assemble and cross-link these nanoballs in situ has been synthesized and structurally characterized. The crystal structure involves 2-fold interpenetration with each framework exhibiting pores of dimensions which vary from less than 1 nm to just over 2.5 nm.

引用

页码：10076 / +

页数：3

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