On the compatibility of polysaccharide/maleic copolymer blends - I. Thermal behaviour of dextran containing blends

被引:14
作者
Bumbu, GG [1 ]
Vasile, C [1 ]
Chitanu, GC [1 ]
Carpov, A [1 ]
机构
[1] Petru Poni Inst Macromol Chem, RO-6600 Iasi, Romania
关键词
dextran; maleic anhydride/acid copolymers; blends; compatibility; thermal behaviour;
D O I
10.1016/S0141-3910(01)00003-9
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The compatibility of dextran (D) with maleic acid-vinyl acetate copolymer (MAc-VA) in the solid state as a thin film has been studied by coupling thermogravimetry and differential scanning calorimetry with infrared spectroscopy. Optical and electron microscopy have been also used to investigate the morphology of the blends. It has been established that blends with a content of dextran higher than 85 wt.% exhibit good compatibility, the morphology of the blends being a homogeneous fine particle dispersion, while blends with a prevalent MAc-VA copolymer content exhibit a tendency to phase separation. (C) 2001 Elsevier Science Ltd. AU rights reserved.
引用
收藏
页码:99 / 108
页数:10
相关论文
共 26 条
[2]   CHROMATOGRAPHY AND PARTITION OF CELLS AND CELL FRAGMENTS [J].
ALBERTSSON, PA .
NATURE, 1956, 177 (4513) :771-774
[3]  
BARANOVSKY YV, 1994, EUR POLYM J, V20, P191
[4]  
BUMBU GG, 1998, 4 INT C HYDR 4 10 OC
[5]  
CARPOV A, 1979, Patent No. 70120
[6]  
CASCONE MG, 1977, J APPL POLYM SCI, V66, P2089
[7]   Analysis and characterization of maleic anhydride copolymers. II. Some aspects of thermo-oxidative decomposition [J].
Chitanu, GC ;
Bumbu, GG ;
Carpov, A ;
Vasile, C .
INTERNATIONAL JOURNAL OF POLYMER ANALYSIS AND CHARACTERIZATION, 1998, 4 (06) :479-500
[8]   Maleic copolymers with pendant disinfectant and or odorant molecules II. Thermal and thermo-oxidative behaviour [J].
Chitanu, GC ;
Bumbu, GG ;
Stoleriu, A ;
Carpov, A ;
Vasile, C ;
Anghelescu-Dogaru, A ;
Rinaudo, M .
POLYMER DEGRADATION AND STABILITY, 1999, 65 (01) :75-85
[9]   Static and dynamic light scattering of maleic acid copolymers [J].
Chitanu, GC ;
Skouri, M ;
Schosseler, F ;
Munch, JP ;
Carpov, A ;
Candaua, SJ .
POLYMER, 2000, 41 (10) :3683-3692
[10]  
CHITANU GC, 1997, C FAC IND CHEM 85 YE