Organosilane-mediated free radical cyclization reactions employing carbonyl traps

被引：17

作者：

Batey, RA ^{[1
]}

MacKay, DB ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Lash Miller Labs, Toronto, ON M5S 3H6, Canada

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 40期

关键词：

D O I：

10.1016/S0040-4039(98)01585-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Free-radical cyclization of halocarbonyl compounds can be achieved using the organosilane reagents phenylsilane and tristrimethylsilylsilane. Both 6-exo-trig and 5-exo-trig cyclizations can be accomplished using aldehydes or ketones as radical traps. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：7267 / 7270

页数：4

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