Recent advances in hydrogen bonding studies involving metal hydrides

被引：73

作者：

Crabtree, RH ^{[1
]}

机构：

[1] Yale Univ, Chem Lab, New Haven, CT 06520 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 557卷 / 01期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0022-328X(97)00738-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Neutral transition metal hydrides tend to act as proton accepters towards conventional H-bond proton donors. The resulting species can be precursors of dihydrogen complexes. The BH bonds of boranes are also effective H-bond accepters. Cationic metal hydrides, in contrast, can act as proton donors toward conventional H-bond accepters, such as OPPh3. (C) 1998 Elsevier Science S.A. All rights reserved.

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页码：111 / 115

页数：5

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